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Praseodymium chloride

Praseodymium chloride

CAS: 10361-79-2

Molecular Formula: Cl3Pr

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Praseodymium chloride - Names and Identifiers

Name Praseodymium chloride
Synonyms PrCl3
NSC 84276
Praseodymium chloride
Praseodymiumtrichloride
Praseodymium trichloride
Praseodymium(III) chloride
praseodymiumchloride(prcl3)
Praseodymium chloride (PrCl3)
PraseodyMiuM(III) chloride, anhydrous, PrCl3
CAS 10361-79-2
EINECS 233-794-4
InChI InChI=1/3ClH.Pr/h3*1H;/q;;;+3/p-3

Praseodymium chloride - Physico-chemical Properties

Molecular FormulaCl3Pr
Molar Mass247.27
Density4,02 g/cm3
Melting Point786°C(lit.)
Boling Point1700°C
Flash Point1700°C
Water SolubilitySoluble in water. (1039g/L) at 13 C.
Vapor Presure33900mmHg at 25°C
Appearancepowder
Specific Gravity4.02
ColorGreen to blue
Merck14,7712
Storage ConditionInert atmosphere,Room Temperature
Stabilityhygroscopic
SensitiveHygroscopic
UseFor the preparation of metal praseodymium and Praseodymium compounds, glass, ceramic coloring

Praseodymium chloride - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant
Risk Codes36 - Irritating to the eyes
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39 - Wear suitable gloves and eye/face protection
WGK Germany2
RTECSTU0175000
TSCAYes
HS Code28469025

Praseodymium chloride - Reference Information

the pure and dry HCl gas is introduced at the speed of 1 cm3/s, and the temperature is maintained at 70 C for 3H, and the temperature is gradually raised to 160 C for 1~2H, the temperature was then slowly raised to 250 ° C. While hot, the furnace was opened to transfer the quartz tube to a desiccator (concentrated sulfuric acid as desiccant), and after cooling, the product was transferred to a hot, dry reagent bottle and sealed quickly. 2 weigh the reactants according to the stoichiometric relationship, and the reactants are packed in a quartz tube (d = 13 ~ 25mm,l = 7 ~ 25cm) suspended in the electric furnace, the electric furnace should be selected so that the temperature of each part of the sample tube is as consistent as possible. The inlet of the reaction tube is connected to the side mouth of the distillation flask (the distillation flask is connected with a polytetrafluoroethylene pipe), and the outlet is connected to the condensation receiver (connected with a polyethylene pipe). The polyethylene pipe needs to be replaced after each experiment, however, the PTFE tube is not affected by the reaction (the device is shown in Fig. CCl4 was added dropwise from the sample tube to the distillation flask at a rate of 0.22 to 0.27g/(min · cm). The flow rate of CCl4 was regulated by a helical clip on a Teflon tube on the distillation flask. The temperature of the distillation flask was maintained at 100 ° C. With an electrothermal shield, and the temperature of the preheating portion (the side tube portion connecting the distillation flask and the reaction tube) was maintained at 120 ° C. With an electrothermal band. The temperature of the reaction furnace is controlled according to the following requirements: 500 C 6H, 550 C 15H, 600~650 C 8H. After completion of the reaction, Ar or other inert gas is charged through an inert gas inlet. Disconnect the reaction tube, match the piston, connect the vacuum system, vacuum, sealed preservation.
EPA chemical substance information information provided by: ofmpeb.epa.gov (external link)
Introduction praseodymium chloride is a blue-green needle-like crystal with a melting point of 786 ℃, a boiling point of 1700 ℃ and a relative density of 4.0225. The heptahydrate is a green triclinic crystal. Deliquescence, melting point 115 ℃, relative density of 2.25417, in the hydrogen chloride atmosphere to 108 ℃ when the loss of 6 molecules of crystal water, 180 ℃ into anhydrous. Both are easily soluble in water, hydrochloric acid and ethanol.
preparation hydrochloric acid and praseodymium dioxide were reacted to obtain praseodymium chloride.
solubility in water (g/100ml) grams dissolved per 100ml of water: 104g/20 ℃
Use used in the preparation of praseodymium metal and Praseodymium compounds, glass, ceramic coloring
research reagents, biochemical Research
used as a petroleum catalyst, can also be used in the production of metal praseodymium.
production method
Last Update:2024-04-10 22:29:15
Praseodymium chloride
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